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By contrast, methane created from petroleum showed no radiocarbon activity because of its age.
The results were summarized in a paper in Science in 1947, in which the authors commented that their results implied it would be possible to date materials containing carbon of organic origin.
The older a sample is, the less (the period of time after which half of a given sample will have decayed) is about 5,730 years, the oldest dates that can be reliably measured by this process date to around 50,000 years ago, although special preparation methods occasionally permit accurate analysis of older samples.
Correcting for isotopic fractionation, as is done for all radiocarbon dates to allow comparison between results from different parts of the biosphere, gives an apparent age of about 440 years for ocean surface water.
Because the time it takes to convert biological materials to fossil fuels is substantially longer than the time it takes for its in the atmosphere, which attained a maximum in 1963 of almost twice what it had been before the testing began.
Measurement of radiocarbon was originally done by beta-counting devices, which counted the amount of beta radiation emitted by decaying atoms in the sample and not just the few that happen to decay during the measurements; it can therefore be used with much smaller samples (as small as individual plant seeds), and gives results much more quickly.
The method was developed by Willard Libby in the late 1940s and soon became a standard tool for archaeologists.
Libby received the Nobel Prize in Chemistry for his work in 1960.